TheBoth arms and legs are usuallyheld in place through a fairly simple compression pin.
A small dab of washing up liquid applied to the joint should lubricate it quite well seated in- avoid oils as they can cause discolouration of the socketsplastic.
If that doesn't work for you, then you could try physically loosening the pins - gently pull the arms out of the sockets and don'tthe legs off the hips and replace them a couple of times tend to come loose unless you repeatedly pull them out,- this is usually enough to compress the arms of the pin enough while still maintaining a grip on the part. Going further you can obviously compress the pins manually and fairly permanently - however this will likely make the joints too loose for your needs - I've certainly got some older minifigs with very wobbly hip joints. I don't remember swapping legs/hips as much as arms as a kid, so I'm reasonably confident that those are more "wear and tear/aging" than the armscan no longer stand up on their own.